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A new general synthesis of halohydrins

✍ Scribed by Giovanni Palumbo; Carla Ferreri; Romualdo Caputo

Book ID: 104217092
Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 218 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)81642-1

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✦ Synopsis

A new synthetic method has been devised for the rapid conversion of epoxides to chZoro-, bromo-and iodo-hydrins in quantitative yield, under miLd conditions and in the absence of protic acids. In connection with other work on the conversion of epoxides to alkenes', we report in this communication some preliminary results concerning a very simple, high yield, general synthesis of chloro-, bromo-and iodo-hydrins which can be effected in a one-pot treatment of epoxides with triphenylphosphine and the proper halogen in anhydrous dichloromethane at room temperature.

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