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Stereocontrolled Synthesis of Unsaturated Halohydrins from Unsaturated Epoxides

✍ Scribed by Díaz, David; Martín, Tomás; Martín, Víctor S.


Book ID
126033554
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
49 KB
Volume
66
Category
Article
ISSN
0022-3263

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Free radical cyclisation of unsaturated
✍ Rosslyn C. Gash; Finlay MacCorquodale; John C. Walton 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 407 KB

## Abstractz The e.s.r. spectra derived from 7-bromo-5.6epoxyheptene derivatives such OS epoxygeranyl bromide (7) showed that the main free radical intermediates were tetrahydr+ranybnethyl radicals (II). formed by ring opening of the epoxide and subsequent exocyclisation of the unsaturated alhoxyl r