Synthesis of α-substituted α,β-unsaturat
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Marcus A Tius; Huaping Hu
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Article
📅
1998
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Elsevier Science
🌐
French
⚖ 190 KB
~-Deprotonation of tert-butyldimethylsilyloxy allene is followed by silyl migration froln oxygen to cm'bon. The resulting C-nucleophile adds to aldehydes to generate cql£uusaturated acylsilanes.