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Reactions of 1,3-dioxacyclanes with acid halides a new synthesis for ω-halohydrine esters

✍ Scribed by Stefan Kwiatkowski; Andrzej Wolinski


Book ID
105079483
Publisher
Springer Vienna
Year
1984
Tongue
English
Weight
116 KB
Volume
115
Category
Article
ISSN
0026-9247

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A new synthesis of 3-substituted-1H-indenes has been developed through the reaction of o-(b-magnesioalkyl)phenylmagnesium dihalides with carboxylate esters, followed by dehydration of the intermediate 1-substituted-1-indanols. Di-Grignard reagents allowing the synthesis of 3-substituted-, 2-methyl-3