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A New Diastereodivergent Synthesis of 1,2-Disubstituted Homopropargylic Alcohols

✍ Scribed by Fabrice Chemla; Nicolas Bernard; Jean Normant

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
349 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis

Disubstituted homopropargylic alcohols can be prepared inversion through the intermediate formation of a bromoallenol moiety. in a diastereodivergent fashion starting from propargylic epoxides by BF 3 -catalysed direct ring-opening or by double served. Thus disubstituted anti homopropargylic alcohols [a] Laboratoire de Chimie des OrganoEle Β΄ments, Universite Β΄P. et M. Curie, Bte 183 the possible participation of the triple bond. The ring open-4 place Jussieu,

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