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A New Chiral Sulfonamide Ligand Based on Tartaric Acid: Synthesis and Application in the Enantioselective Addition of Diethylzinc to Aldehydes and Ketones.

✍ Scribed by Ailing Hui; Jintang Zhang; Jinmin Fan; Zhiyong Wang


Publisher
John Wiley and Sons
Year
2007
Weight
36 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Synthesis and application of chiral Ξ²-am
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## Abstract A new class of chiral β‐amino disulfides was synthesized from readily available and inexpensive starting materials by a straightforward method and their abilities as ligands were examined in the enantioselective addition of diethylzinc to aldehydes. Enantiomeric excesses of up to 99% ha