Synthesis of a Chiral Tridentate Ligand from Proline and Its Application to Enantioselective Addition of Diethylzinc to Aldehydes
β Scribed by Qiu Li-Hua; Shen Zong-Xuan; Ge Jian-Feng; Zhang Ya-Wen
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 51 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0256-7660
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## Abstract A new class of chiral Ξ²βamino disulfides was synthesized from readily available and inexpensive starting materials by a straightforward method and their abilities as ligands were examined in the enantioselective addition of diethylzinc to aldehydes. Enantiomeric excesses of up to 99% ha