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A new chiral diol derived from tetralone for the complexation of Lewis acids

✍ Scribed by Michael P Coogan; Robert Haigh; Adrian Hall; Lisa D Harris; David E Hibbs; Robert L Jenkins; Claire L Jones; Nicholas C.O Tomkinson


Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
200 KB
Volume
59
Category
Article
ISSN
0040-4020

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We have shown that association of a bulky silicon group with the bis(trifluoromethanesulfonyl)imide leaving group unexpectedly enhances the electrophilic character of the R 3 SiNTf 2 silylating agent. The presence of a chiral substituent derived from (-)-myrtenal on the silicon atom led to a Lewis a