Stereochemical Change in the Lewis Acid-Promoted Reaction of 2-Siloxypyrrole Derived from (L)-Glutamic Acid. Synthesis of a Lactacystin Analogue. -The enantiopure pyrrolooxazole (I) react with aliphatic aldehydes [cf. (II)] stereoselectively to yield either the isomers (IV) or (VIII) as major produ
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ChemInform Abstract: Chiral Lewis Acid Controlled Synthesis (CLAC Synthesis): Chiral Lewis Acids Influence the Reaction Course in Asymmetric Aldol Reactions for the Synthesis of Enantiomeric Dihydroxythioester Derivatives in the Presence of Chiral Diamines Derived from L-Proline.
✍ Scribed by S. KOBAYASHI; M. HORIBE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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