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A mild procedure for the production of secondary amines from oximes and benzisoxazoles

โœ Scribed by Mark Searcey; Sukhwant S. Grewal; Fiorenza Madeo; Petros G. Tsoungas

Book ID
104254221
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
156 KB
Volume
44
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

2-Hydroxybenzaldoximes are reduced under mild conditions of ammonium formate/Pd-C in methanol to give secondary amines. Benzisoxazoles react under the same mild conditions to give the same products. A possible mechanism is suggested, involving the intermediacy of the benzisoxazole in the oxime conversion.

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