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A Mild Procedure for the Production of Secondary Amines from Oximes and Benzisoxazoles.

โœ Scribed by Mark Searcey; Sukhwant S. Grewal; Fiorenza Madeo; Petros G. Tsoungas

Book ID
101957432
Publisher
John Wiley and Sons
Year
2003
Weight
110 KB
Volume
34
Category
Article
ISSN
0931-7597

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A mild procedure for the production of s
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2-Hydroxybenzaldoximes are reduced under mild conditions of ammonium formate/Pd-C in methanol to give secondary amines. Benzisoxazoles react under the same mild conditions to give the same products. A possible mechanism is suggested, involving the intermediacy of the benzisoxazole in the oxime conve

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