A mild procedure for the reduction of aliphatic nitro compounds to oximes
โ Scribed by Derek H.R. Barton; Isabel Fernandez; Caroline S. Richard; Samir Z. Zard
- Book ID
- 104205069
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 535 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4020
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โฆ Synopsis
Aliphotic nitro compounds react with CWbon disulphide in the presence of triethylomine to give the corresponding oximes in moderate to good yields.
๐ SIMILAR VOLUMES
The carbonyl and nitro functional groups play a major role in organic synthesis. I, 2 The efficient replacement of one by the other, which enhances this utility, is readily accomplished in the nitro to carbonyl direction. However, the conversion of carbonyl to nitro groups, which is generally effec
Various aliphatic and aromatic nitro compounds were selectively and rapidly reduced to their corresponding amino derivatives in very good yield using anhydrous ammonium formate as a catalytic hydrogen transfer agent.
Useful Oxidation Procedure of Oximes to Nitro Compounds with Benz-Mo in Acetonitrile. -The conversion of a variety of oximes (I) to nitroalkanes (II) is achieved by a molybdenium(VI) oxodiperoxo complex as oxidant. The reagent ratios shown are necessary for the decrease of the parent carbonyl compo