ChemInform Abstract: Useful Oxidation Procedure of Oximes to Nitro Compounds with Benz-Mo in Acetonitrile.

✍ Scribed by F. P. BALLISTRERI; E. BARBUZZI; G. A. TOMASELLI; R. M. TOSCANO

• Book ID: 101847747
• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 28 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199715057

✦ Synopsis

Useful Oxidation Procedure of Oximes to Nitro Compounds with Benz-Mo in Acetonitrile.

-The conversion of a variety of oximes (I) to nitroalkanes (II) is achieved by a molybdenium(VI) oxodiperoxo complex as oxidant. The reagent ratios shown are necessary for the decrease of the parent carbonyl compounds.

-(BALLISTRERI, F. P.; BARBUZZI, E.;