A Mild Radical Procedure for the Reduction of B-Alkylcatecholboranes to Alkanes.
β Scribed by Davide Pozzi; Eoin M. Scanlan; Philippe Renaud
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 25 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Selective and efficient generation of alkyl radicals from alkenes as well as their addition to unsaturated ketones and aldehydes is reported. The method is based on a simple one-pot procedure involving the hydroboration of the alkene with catecholborane, followed by treatment with a catalytic amount