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A mild and convenient procedure for the N-formylation of secondary amines using organosilicon chemistry

✍ Scribed by Djuric, Stevan W.


Book ID
111644745
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
236 KB
Volume
49
Category
Article
ISSN
0022-3263

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A mild procedure for the production of s
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2-Hydroxybenzaldoximes are reduced under mild conditions of ammonium formate/Pd-C in methanol to give secondary amines. Benzisoxazoles react under the same mild conditions to give the same products. A possible mechanism is suggested, involving the intermediacy of the benzisoxazole in the oxime conve