Rcceivcd 10 hlarch 1977 WC concldcr the contrlbutlon of rnolc~ular rotntlon to tbc vlbrationnl reLuatton of rnolcculcc in crystalline mxha An m.ilysls of rc.W.tl:: mtcra\_ttons Ic.~dr to tbc mtroduction of d rnodcl one hmng the cacntml pbysxnl fcdturcs. When tbc rotational mcchmisrn I\ donimant, the
A mechanism for carbon-hydrogen vibrational relaxation in alkanes
β Scribed by Hutchinson, John S.; Hynes, James T.; Reinhardt, William P.
- Book ID
- 120188334
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 633 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A previous mode1 for calculating the cross sections of the vibrational excitation of carbon monoxide by collision with carbon monoxide has been improved to include anharmonicity effects in the vibrational wavefunctions by describing them in terms of Morse oscillators. It is shown that this leads to
A collision model for thevibrational relaxation of hydrogen fluoride at low temperatures is proposed. Because of the contribution of a strong hydrogen-bond attraction, the molecules are considered to undergo oscillatory motion about their equitibrium orientations This motion is taken to be primarily