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Anharmonicity effect on vibrational relaxation in carbon monoxide

✍ Scribed by A. Joanna Taylor; F.A. Gianturco

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
290 KB
Volume
4
Category
Article
ISSN
0009-2614

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✦ Synopsis

A previous mode1 for calculating the cross sections of the vibrational excitation of carbon monoxide by collision with carbon monoxide has been improved to include anharmonicity effects in the vibrational wavefunctions by describing them in terms of Morse oscillators.

It is shown that this leads to further improvement in the agreement between the theoretical and experimental values for the ribrntional relaxation times. The sensitivity of the total cross sections to nnharmonicity is investigated at several collision energies and further lines of approach are suggested.

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