✦ LIBER ✦

Rotational mechanism for vibrational relaxation in rigid media

✍ Scribed by Karl F. Freed; Horia Metiu

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 425 KB
Volume: 48
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80311-4

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✦ Synopsis

Rcceivcd 10 hlarch 1977 WC concldcr the contrlbutlon of rnolc~ular rotntlon to tbc vlbrationnl reLuatton of rnolcculcc in crystalline mxha An m.ilysls of rc.W.tl:: mtcra_ttons Ic.~dr to tbc mtroduction of d rnodcl one hmng the cacntml pbysxnl fcdturcs. When tbc rotational mcchmisrn I\ donimant, the rate varies cxponcntmlly wltb (w/B)"' For w/B Ixgc, wbcrc w 1s the oscdhtor frcqucncy and ,!I I\ the rot.ltlon.;l constmt, whk the rate IF mdcpcndcnt of tcmpcmturc .lt least up to tcmpcratures ==20 hB/kR

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