Vibrational and rotational relaxation in hydrogen sulfide
โ Scribed by H.-J. Bauer; A.C.C. Paphitis; R. Schotter
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 225 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0031-8914
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Rcceivcd 10 hlarch 1977 WC concldcr the contrlbutlon of rnolc~ular rotntlon to tbc vlbrationnl reLuatton of rnolcculcc in crystalline mxha An m.ilysls of rc.W.tl:: mtcra\_ttons Ic.~dr to tbc mtroduction of d rnodcl one hmng the cacntml pbysxnl fcdturcs. When tbc rotational mcchmisrn I\ donimant, the
Wxational relaxation in Hz-rare-gases mixtures has been studied, using the Raman escitation of Ha. The mea% urements performed on binary and ternary Hz-He-h mixtures yiAded the following rates at room temperature: prHz-He = 2280 psec atm , ~TH,,\_A~' 7150 pSCC Zltm . . The Hz-He value obtained here