A luminescent gold complex: bis-μ-[bis(dicyclohexylphosphino)ethane-P,P']-digold bis(hexafluorophosphate)
✍ Scribed by Schaefer, W. P. ;Marsh, R. E. ;McCleskey, T. M. ;Gray, H. B.
- Book ID
- 114508675
- Publisher
- International Union of Crystallography
- Year
- 1991
- Tongue
- English
- Weight
- 471 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
In the title complex, [Au(C 26 H 48 P 2 ) 2 ]ClÁ4CHCl 3 , the cation and anion lie on twofold rotation axes. The Au atom has a distorted tetrahedral coordination geometry, with two chelating diphosphine ligands, and lies far from the anion.
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.008 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.036 wR factor = 0.087 Data-to-parameter ratio = 23.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org