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A general method for the asymmetric synthesis of α-amino acids by the alkylation of glycine in chiral Ni(II) complexes

✍ Scribed by Yu. N. Belokon'; N. I. Chernoglazova; N. S. Garbalinskaya; M. B. Saporovskaya; K. A. Kochetkov; V. M. Belikov


Book ID
112447220
Publisher
Springer
Year
1986
Tongue
English
Weight
232 KB
Volume
35
Category
Article
ISSN
1573-9171

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Asymmetric synthesis of uncommon α-amino
✍ Kiyoshi Tanaka; Mija Ahn; Yukari Watanabe; Kaoru Fuji 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 669 KB

For the purpose of practical preparations of a variety of enantiomerically pure uncommon ¢x-amino acids, alkylations of the chiral glycine equivalent 5, which possesses axially chiral binaphthol as an auxiliary, with several electrophiles were investigated. The alkylation proceeded smoothly in satis