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ChemInform Abstract: Asymmetric Synthesis of Uncommon α-Amino Acids by Diastereoselective Alkylations of a Chiral Glycine Equivalent.

✍ Scribed by K. TANAKA; M. AHN; Y. WATANABE; K. FUJI


Book ID
112038057
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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Asymmetric synthesis of uncommon α-amino
✍ Kiyoshi Tanaka; Mija Ahn; Yukari Watanabe; Kaoru Fuji 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 669 KB

For the purpose of practical preparations of a variety of enantiomerically pure uncommon ¢x-amino acids, alkylations of the chiral glycine equivalent 5, which possesses axially chiral binaphthol as an auxiliary, with several electrophiles were investigated. The alkylation proceeded smoothly in satis