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Improved Synthesis of Proline-Derived Ni(II) Complexes of Glycine: Versatile Chiral Equivalents of Nucleophilic Glycine for General Asymmetric Synthesis of α-Amino Acids

✍ Scribed by Ueki, Hisanori; Ellis, Trevor K.; Martin, Collin H.; Boettiger, Tomas U.; Bolene, Shawna B.; Soloshonok, Vadim A.


Book ID
119945828
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
53 KB
Volume
68
Category
Article
ISSN
0022-3263

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Asymmetric synthesis of uncommon α-amino
✍ Kiyoshi Tanaka; Mija Ahn; Yukari Watanabe; Kaoru Fuji 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 669 KB

For the purpose of practical preparations of a variety of enantiomerically pure uncommon ¢x-amino acids, alkylations of the chiral glycine equivalent 5, which possesses axially chiral binaphthol as an auxiliary, with several electrophiles were investigated. The alkylation proceeded smoothly in satis