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A Fragmentational Approach to Macrolides: (5-E, 8-Z)-6-methyl-5,8-undecadien-11-olide

✍ Scribed by Dr. Daniel Sternbach; dipl. Ing.-Chem. Fritz Jaisli; dipl. sc. nat. Marco Bonetti; Prof. Dr. Albert Eschenmoser; Prof. Dr. Masayuki Shibuya

Book ID: 101549581
Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 316 KB
Volume: 18
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.197906341

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**Eine decarboxylative Doppelfragmentierung** vom Typ __A__ ist der Schlüsselschritt bei der Synthese des ungesättigten Lactons (__2__) aus dem Amidiniumsalz (__1__). Auch das Diastereomer von (__1__) ergibt (__2__). Analog kann das isomere Lacton (__3__) aus diastereomeren Amidiniumsalzen erhalten

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