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ChemInform Abstract: Structure Elucidation and Synthesis of (4S,5S,6Z,8E)-5-Hydroxydeca-6,8-dien-4-olide [(S,S)-Sapinofuranone B] — A Novel γ-Lactone Metabolite of Acremonium strictum.

✍ Scribed by Sarah Clough; Mairi E. Raggatt; Thomas J. Simpson; Christine L. Willis; Andrew Whiting; Stephen K. Wrigley

Publisher: John Wiley and Sons
Year: 2000
Weight: 33 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200048231

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Crystal Structures of 3.0.CO;2-Z/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l6migq&s=c6023d23614cc5febe987fafc1b321310df66e88" class="inlineGraphic">{[Cd(phen)](C6H8O4)3/3} and 3.0.CO;2-Z/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l6migr&s=ca7048152611c2fb5494587a82e9d48966405110" class="inlineGraphic">{[Cd(phen)](C7H10O4)3/3} · 2H2O with C6H10O4 = Adipic Acid and C7H12O4 = Pimelic Acid

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Two coordination polymers 1 ϱ {[Cd(phen)](C 6 H 8 O 4 ) 3/3 } (1) and 1 ϱ {[Cd(phen)](C 7 H 10 O 4 ) 3/3 } • 2H 2 O (2) were structurally characterized by single crystal X-ray diffraction methods. In 1 (C2/ c (no. 15), a ϭ 16.169(2) A ˚, b ϭ 15.485(2) A ˚, c ϭ 14.044(2) A ˚, β ϭ 112.701(8)°, U ϭ 324