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A facile synthesis of an aminal of bicyclo[3.1.0]hexan-6-one and of endo-6-piperidinobicyclo[3.1.0]hexane

โœ Scribed by J. Szmuszkovicz; E. Cerda; M.F. Grostic; J.F. Zieserl Jr.

Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
188 KB
Volume
8
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

6-Amino substituted bicycld3.l.O]hexane derivatives are relatively rare.1r2~9~4

We wish to report preliminary results on the facile two-step synthesis of endo-6-piperidino-bicycld3.l.~hexane (IV).

๐Ÿ“œ SIMILAR VOLUMES

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Flash vacuum pyrolysis and matrix-isolation studies of 6bromo-6-(trimethylstannyl)bicyclo[3.l.Olhexane (1) gave evidence for the formation of 1,2-c.yclohexadiene (2) from this precursor. At high temperatures (>6OO'C) 2 is not stable and fragmentates to I-butene-3yne (4) and ethylene.