๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Conformational investigations of 6-EXO and 6-ENDO- methylbicyclo[3.1.0] hexan-3-one

โœ Scribed by T. Richter; Elliott Bay; J.W. Bevan

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
397 KB
Volume
73
Category
Article
ISSN
0022-2860

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Exo- and endo-6-chlorobicyclo[3.1.0]hexa
Exo- and endo-6-chlorobicyclo[3.1.0]hexanes
โœ M.S. Baird; C.B. Reese ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 181 KB

Reaction between cyclopentene and chlorocarbene (1) in ether solution at 20' gave exo--and endo-6-chlorobicyclo[j.l.O!hexanes (I and II, respectively), in ~a. 35% combined yields. The more abundant isomer (~a. 75% of the mixture) was isolated by preparative g.l.c., and characterized as a chlorocarbe

A facile synthesis of an aminal of bicyc
A facile synthesis of an aminal of bicyclo[3.1.0]hexan-6-one and of endo-6-piperidinobicyclo[3.1.0]hexane
โœ J. Szmuszkovicz; E. Cerda; M.F. Grostic; J.F. Zieserl Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 188 KB

6-Amino substituted bicycld3.l.O]hexane derivatives are relatively rare.1r2~9~4 We wish to report preliminary results on the facile two-step synthesis of endo-6-piperidino-bicycld3.l.~hexane (IV).

Thermal reactions of endo- and exo-6-met
Thermal reactions of endo- and exo-6-methylbicyclo[3.2.0]hept-2-enes: an experimental test for a potential ring inversion
โœ John E Baldwin; Phyllis A Leber ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 76 KB

endo-6-Methylbicyclo[3.2.0] hept-2-ene at 275ยฐC in the gas phase isomerizes and fragments with a first-order rate constant for disappearance of 7.3 ร—10 -6 s -1 . The exo-methyl isomer is not formed; the ring inversion isomerization of the bicyclo[3.2.0]hept-2-ene is not kinetically competitive.