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6-bromo-6-(trimethylstannyl)bicyclo[3.1.0]hexane as a thermal precursor of 1,2-cyclohexadiene

✍ Scribed by Andreas Runge; Wolfram Sander

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 218 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)85340-x

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✦ Synopsis

Flash vacuum pyrolysis and matrix-isolation studies of 6bromo-6-(trimethylstannyl)bicyclo[3.l.Olhexane

(1) gave evidence for the formation of 1,2-c.yclohexadiene (2) from this precursor. At high temperatures (>6OO'C) 2 is not stable and fragmentates to I-butene-3yne (4) and ethylene.

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