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A direct route to medium and large cyclic amines from aminoalkenes

✍ Scribed by David J. Bergmann; Eva M. Campi; W.Roy Jackson; Antonio F. Patti; Dilek Saylik

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
210 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Rhodium-catalysed reactions of aminoalkenes with H2/CO give cyclic amines with a range of medium and large ring sizes in yields up to 85%. High regioselectivity for non-branched products can be obtained when BIPHEPHOS is used as a ligand in the hydroformylation reaction.

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