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ChemInform Abstract: A Direct, Highly Convergent Route to α-Methylene-γ-lactones Fused to Medium and Large Rings.

✍ Scribed by Leo A. Paquette; Jose Mendez-Andino


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Direct Route to M
✍ David J. Bergmann; Eva M. Campi; W. Roy Jackson; Antonio F. Patti; Dilek Saylik 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

A Direct Route to Medium and Large Cyclic Amines from Aminoalkenes. -Rhodium-catalyzed hydroformylation of N-substituted alkenylamines in the presence of the bulky BIPHEPHOS ligand leads to formation of medium and large cyclic amines, e.g. (III), (V), and (VII). Important side reactions include hyd