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A convenient technique for the measurement and assignment of long-range carbon-13 proton coupling constants

✍ Scribed by James Keeler; David Neuhaus; Jeremy J. Titman

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
383 KB
Volume
146
Category
Article
ISSN
0009-2614

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✦ Synopsis

A new technique is described which enables accurate values of heteronuclear long-range coupling constants to be obtained from highly distorted multiplets in two-dimensional correlation spectra. The technique uses a simple data fitting of the distorted multiplet with a model obtained from the conventional proton spectrum, and achieves high sensitivity by detecting the signals at the proton frequency.

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