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Assignment of carbon-13 NMR spectra and sign determination of long range carbon-13—proton coupling constants with SPI

✍ Scribed by A. A. Chalmers; K. G. R. Pachler; P. L. Wessels

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
244 KB
Volume
6
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The application of selective population inversion (SPI) to the assignment of ^13^C resonances and to the determination of the relative sign of ^13^C^1^H coupling constants is demonstrated for 1‐phenyl‐1,2‐dibromo‐2‐nitroethane. A negative sign for the geminal C‐2H‐1 coupling constant has been determined from the ^13^C spectra. The relationship between SPI and TSI is discussed.

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