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Carbon-13 and proton spectra of tetracyclododecanes: Long-range steric effects

✍ Scribed by P. R. Seidl; K. Z. Leal; V. E. U. Costa; N. D. Poli


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
415 KB
Volume
28
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The ^1^H and ^13^C spectra of endo‐endo‐tetracyclo[6.1.1^3,6^.0^2,7^]dodec‐4‐en‐10‐ol have been interpreted using shift reagents and HETCOR experiments. Carbon chemical shifts are compared with tetracyclic analogs and bicyclic model compounds. Evidence for upfield δ and ε effects of 3–5 ppm is presented.


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