One-Dimensional Inverse-Detected Methods for Measurement of Long-Range Proton-Carbon Coupling Constants. Application to Saccharides

Application of 1D BIRD or X-filtered DEP

Application of 1D BIRD or X-filtered DEPT long-range CC relay for detection of proton and carbon via four bonds and measuring long-range 13C13C coupling constants

✍ Eri Fukushi; Jun Kawabata 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 1 views

We propose the 13 C-detecting 1D DEPT long-range C-C relay to detect super long-range H-C connectivity via four bonds ( 1 H-13 C-X-X-13 C, X represents 12 C or heteronuclear). It is derived from the DEPT C-C relay which detects the H-C correlations via two bonds ( 1 H-13 C-13 C) by setting the delay