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Measurement of long-range proton–carbon coupling constants from pure in-phase 1D multiplets

✍ Scribed by Juan F. Espinosa; Paloma Vidal; Teodor Parella; Sergi Gil

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
201 KB
Volume
49
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The SELective INverse detection of carbon–proton CORrelation pulse sequence that yields a 1D spectrum of a proton directly bonded to a selected carbon resonance has been converted into a proton and carbon double‐selective variant that provides a ^1^H spectrum of a selected proton that is long‐range coupled to a specific carbon resonance. The resulting 1D proton multiplet exhibits a pure absorptive in‐phase lineshape for precise measurement of specific long‐range proton–carbon coupling constants in small organic molecules at natural abundance. Copyright © 2011 John Wiley & Sons, Ltd.

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