A convenient synthesis of (2S,3R,6S,7Z)- and (2R,3S,6S,7Z)-2,3-epoxy-7,10-bisaboladiene, the sex pheromones of the southern green stink bug (Nezara viridula)
β Scribed by Shigefumi Kuwahara; Daisuke Itoh; Walter Soares Leal; Osamu Kodama
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 613 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
β¦ Synopsis
A Convenient Synthesis of (2S,3R,KS,7Z)and (2R,3S,6S,7Z)-2,3-Epoxy-7,10-bisaboladiene, the Sex Pheromones of the Southern Green Stink Bug (Nezara viridula
π SIMILAR VOLUMES
## Abstract Faranal (1), the trailβfollowing pheromone of the worker of Pharaoh's ant (__Monomorium pharaonis__), was synthesized by the coupling reaction of the iododiene 3 with the chiral building block 8 as the key step. The geometrically pure iododiene 3 was prepared by the zirconoceneβmediated
## Abstract (3__S__,7__R__,8__E__,10__E__)β3,7,9βTrimethylβ8,10βdodecadienβ6βone (1), the major component of the femaleβproduced sex pheromone of the maritime pine scale (__Matsucoccus feytaudi__), was synthesized by starting from epoxide 2, which was obtained from __meso__β__epoxy__ diacetate (F)
Synthesis of the chiral bicyclic ketone mentioned in the title starting from Rcarvone, and its elaboration to 7-epibakkenolide-A is described. Conjugate addition of dimethyl copperlithium to R-carvone followed by alkylation of the intermediate enolate generated the allylated compound 6, which was tr
## Abstract The structure of the antibacterial sesquiterpene from __Premna oligotricha__ was shown to be not 1 but 2 (relative stereochemistry) by the unambiguous synthesis of both (Β±)β1 and (Β±)β2.