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Synthesis of Mono- and Sesquiterpenoids, XXV. Synthesis of (6R*,7R*)-7-Hydroxy-6,11-cyclofarnes-3(15)-en-2-one, the Racemate of the Antibacterial Sesquiterpene from Premna oligotricha, and Its (6R*,7S*) Isomer

✍ Scribed by Yajima, Arata ;Takikawa, Hirosato ;Mori, Kenji


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
749 KB
Volume
1996
Category
Article
ISSN
0947-3440

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✦ Synopsis


Abstract

The structure of the antibacterial sesquiterpene from Premna oligotricha was shown to be not 1 but 2 (relative stereochemistry) by the unambiguous synthesis of both (Β±)‐1 and (Β±)‐2.


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ChemInform Abstract: Synthesis of Mono-
✍ Sayo Horiuchi; Hirosato Takikawa; Kenji Mori πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB

Synthesis of Mono-and Sesquiterpenoids. Part 27. Synthesis of (6S,7S)-7-Hydroxy-6,11-cyclofarnes-3(15)-en-2-one (IV), the Opposite Enantiomer of the Antibacterial Sesquiterpene from Premna oligotricha, and the (R) Enantiomer (IX) of Ancistrodial, the Defensive Sesquiterpene from Ancistrotermes cavit