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ChemInform Abstract: Synthesis of Mono- and Sesquiterpenoids. Part 27. Synthesis of (6S,7S)-7-Hydroxy-6,11-cyclofarnes-3(15)-en-2-one (IV), the Opposite Enantiomer of the Antibacterial Sesquiterpene from Premna oligotricha, and the (R) Enantiomer (IX) of Ancistrodial, the Defensive Sesquiterpene from Ancistrotermes cavithorax.

✍ Scribed by Sayo Horiuchi; Hirosato Takikawa; Kenji Mori

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199916193

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✦ Synopsis

Synthesis of Mono-and Sesquiterpenoids. Part 27. Synthesis of (6S,7S)-7-Hydroxy-6,11-cyclofarnes-3(15)-en-2-one (IV), the Opposite Enantiomer of the Antibacterial Sesquiterpene from Premna oligotricha, and the (R) Enantiomer (IX) of Ancistrodial, the Defensive Sesquiterpene from Ancistrotermes cavithorax.

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## Abstract The structure of the antibacterial sesquiterpene from __Premna oligotricha__ was shown to be not 1 but 2 (relative stereochemistry) by the unambiguous synthesis of both (±)‐1 and (±)‐2.