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A convenient high yield synthesis of nitroxides

โœ Scribed by Robert W. Murray; Megh Singh

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
166 KB
Volume
29
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Appropriate secondary amines are readily converted to nitroxides by dimethyldioxirane in a rapid, convenient, and essentially quantitative process.

We earlier reported2 that dimethyldioxirane3, 1, oxidizes primary amines to nitro compounds in a facile, high yield process. While continuing our work involving the reactions of 1 with nitrogen-containing substrates we have dis-

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Tris(diethylamino)phosphlne affords tertiary (amino) phosphines of pyrrolidlne, piperldine, liZGiXiyleneimine, morpholine and N-methylpiperazlne In nearly quantitative yields by transamlnation route -an easy and convenient synthesis occurlng under mild conditions. The versat.ility of tertiary phosp