A convenient low-pressure, high-yield synthesis of Ir4(CO)12
โ Scribed by G.F. Stuntz; J.R. Shapley
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 107 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0020-1650
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๐ SIMILAR VOLUMES
Appropriate secondary amines are readily converted to nitroxides by dimethyldioxirane in a rapid, convenient, and essentially quantitative process. We earlier reported2 that dimethyldioxirane3, 1, oxidizes primary amines to nitro compounds in a facile, high yield process. While continuing our work
Tris(diethylamino)phosphlne affords tertiary (amino) phosphines of pyrrolidlne, piperldine, liZGiXiyleneimine, morpholine and N-methylpiperazlne In nearly quantitative yields by transamlnation route -an easy and convenient synthesis occurlng under mild conditions. The versat.ility of tertiary phosp