A convenient and high yield synthesis of tertiary (amino) phosphines by transamination route

✍ Scribed by L.Altaf Hussain; Anil J. Elias; M.N.Sudheendra Rao

• Publisher: Elsevier Science
• Year: 1988
• Tongue: French
• Weight: 217 KB
• Volume: 29
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)82246-7

✦ Synopsis

Tris(diethylamino)phosphlne affords tertiary (amino) phosphines of pyrrolidlne, piperldine, liZGiXiyleneimine, morpholine and N-methylpiperazlne In nearly quantitative yields by transamlnation route -an easy and convenient synthesis occurlng under mild conditions.

The versat.ility of tertiary phosphlnes as llgands in organometalllc and coordination chemistry