## Abstract 2‐(__tert__‐Butyl)‐3,7‐dehydrotropone (7‐(__tert__‐butyl)bicyclo[3.2.0]hepta‐1(7),2,4‐trien‐6‐one; **1**) was found to dimerize reversibly to **2A** by [2 + 4]‐cycloaddition/cycloreversion reaction. The equilibrium lies on the side of the highly strained dimer **2A** in the solid state,
7-(p-Tolylsulfonyl)-7-azabicyclo[4.1.0]heptane
✍ Scribed by Yang, Zhen ;Zhang, Ming-Jie ;Zhu, Jie
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 126 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C~13~H~17~NO~2~S, is an aziridination product of cyclohexene using chloramine-T as a substrate. The aziridine ring is axially bound to the cyclohexane ring, which has a disordered half-chair-like conformation.
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