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The decomposition of exo-7-azidobicyclo [4.1.0] heptane

✍ Scribed by D.S. Wulfman; T.R. Steinheimer


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
180 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis


The reported decomposition of dichlorocyclopropyl azides to yield dichloro-lazetinesl prompts us to report our related results with norcaranyl azides.


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7-(p-Tolyl­sulfon­yl)-7-aza­bicyclo­[4.1
✍ Yang, Zhen ;Zhang, Ming-Jie ;Zhu, Jie 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 126 KB

The title compound, C~13~H~17~NO~2~S, is an aziridination product of cyclohexene using chloramine-T as a substrate. The aziridine ring is axially bound to the cyclohexane ring, which has a disordered half-chair-like conformation.