Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.049 wR factor = 0.145 Data-to-parameter ratio = 9.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
6,6′-Dichloro-3,3′-(butane-1,4-diyldioxy)diflavone
✍ Scribed by Thinagar, S. ;Velmurugan, D. ;Gupta, S. C. ;Merazig, H. ;Bouacida, S.
- Book ID
- 104479943
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 183 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Molecules of the title compound, C 34 H 24 Cl 2 O 6 , lie across crystallographic inversion centres. The ¯avone moiety is slightly folded, with the benzene and dihydropyrone rings making a dihedral angle of 2.5 (2) . In the crystal, the molecules exist as cyclic intermolecular CÐHÁ Á ÁCl hydrogenbonded dimers. The structure is further stabilized by van der Waals interactions.
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The title compound, C 10 H 14 N 2 S 4 , was synthesized by the reaction of the potassium salt of 2-thiothiazole and 1,4dibromobutane. The two 2-thiazolethio groups are related by a center of symmetry. The plane de®ned by the butyl carbon chain is approximately orthogonal to the thiazole plane, with
The reaction of endo-cis-7-oxabicyclo[2.2.1]hept-5-ene-2,3diol with BCl 3 followed by acetylation with acetyl chloride gives dichloroconduritol derivatives. The crystal structure of the title compound, C 10 H 12 Cl 2 O 4 , has been investigated. The cyclohexene ring adopts a distorted half-chair con