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4,4,6,6-Tetra­chloro-1′,3′-[2,2′-(3-oxapentane-1,5-dioxy)­di­benzyl]-2λ5,4λ5,6λ5-cyclo­triphosphazene-2-spiro-2′-1,3,2-di­aza­phospho­lane benzene hemisolvate

✍ Scribed by Tercan, Barış ;Hökelek, Tuncer ;Bilge, Selen ;Demiriz, Şemsay ;Kılıç, Zeynel

Book ID
111752033
Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
326 KB
Volume
60
Category
Article
ISSN
1600-5368

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The condensation reactions of N 2 O x (xZ2, 3) donor type bifunctional aminopodands 1-4 with hexachlorocyclotriphosphazatriene, N 3 P 3 Cl 6 , have been investigated and the partly substituted 5-8 novel spiro-cyclic phosphaza (PNP) lariat ethers, having various different ring sizes between 11 and 14

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The title compound, C 26 H 16 Cl 2 N 7 O 12 P 3 .C 2 H 3 N, consists of a non-planar trimeric phosphazene ring and two bulky 2,2 Hmethylenebis(4-nitrophenoxy) side groups, two cis-Cl atoms, and an acetonitrile molecule as solvent. With respect to the corresponding values in the reference compound N