6-Chloro-4-(dimethylaminomethyleneamino)-2-(methylsulfanyl)pyrimidine
✍ Scribed by Torre, José M. de la ;Cobo, Justo ;Nogueras, Manuel ;Low, John Nicolson
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 241 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 27 H 24 ClN 3 O 6 , a probable new herbicide, was synthesized by the reaction of 4,6-dimethoxy-2-(methylsulfonyl)pyrimidine and methyl 4-[2-chloro-4-(2-hydroxybenzylamino)phenoxy]benzoate in tetrahydrofuran. -Interactions occur between neighbouring benzene rings.
The title compound, C~25~H~24~N~2~O~3~S~3~, was crystallized from a methanol–acetone mixture. The monoclinic structure features one molecule in the asymmetric unit. The crystal packing is stabilized by π stacking.
In the molecule of the title compound, C 15 H 13 ClN 2 O 4 , the pyrimidine and benzene rings form a dihedral angle of 69.3 (3) . Nostacking interactions are observed in the crystal structure.