Employmg snmplcs cnrichcd to >90% in 57Fc, hlbssbducr cffcct studlcs dcmonstratc that high-spin (%2) := low-spm ('A1) transitions arc responsible for the peculiar tempcraturc dcpendcncc of the mdgnctlsm in ccrtam [fc(paptH)z ] X2 l nH20 complcxcs where paptH = 2-(2-pyridyhho) -4-(2-pyrldyl)thiai!olc
✦ LIBER ✦
5T2-1A1 Spin transition and residual paramagnetism in bis(2,4-bis(2-pyridyl)thiazole)iron(II) complexes: mössbauer effect and magnetism
✍ Scribed by E. König; G. Ritter; H.A. Goodwin
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 798 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0301-0104
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Magnetic suswptibilities down to 1.2"K and 57Fe Miissbauer spectra at 42°K are reported on [Fe(pten)2 OR] \* 5H20. The results are consistent with a 3Az(~z~2~~)ground state characterized by a zero-field splitting of D = 4.150 cm-' into an upper !&Ys= +l) and a lower 10) level andg = 2.80. In reasona