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Mössbauer effect study on low-spin 1A1 ⇌ high-spin 5T2 transition in tris(2-picolylamine) iron chloride I. Dilution effect in [FexZn1-x(2-pic)3]Ch2·C2H5OH

✍ Scribed by M. Sorai; J. Ensling; P. Gütlich


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
823 KB
Volume
18
Category
Article
ISSN
0301-0104

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📜 SIMILAR VOLUMES


Thermally induced high-spin (5T2) ⇌ low-
✍ E. König; G. Ritter; H.A. Goodwin 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 403 KB

Employmg snmplcs cnrichcd to >90% in 57Fc, hlbssbducr cffcct studlcs dcmonstratc that high-spin (%2) := low-spm ('A1) transitions arc responsible for the peculiar tempcraturc dcpendcncc of the mdgnctlsm in ccrtam [fc(paptH)z ] X2 l nH20 complcxcs where paptH = 2-(2-pyridyhho) -4-(2-pyrldyl)thiai!olc