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Mössbauer effect and magnetism down to 1.2°K in the triplet ground state of an iron(II)—phenanthroline complex

✍ Scribed by E. König; B. Kanellakopulos


Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
312 KB
Volume
12
Category
Article
ISSN
0009-2614

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✦ Synopsis


Magnetic suswptibilities down to 1.2"K and 57Fe Miissbauer spectra at 42°K are reported on [Fe(pten)2 OR] * 5H20. The results are consistent with a 3Az(~z~2~~)ground state characterized by a zero-field splitting of D = 4.150 cm-' into an upper !&Ys= +l) and a lower 10) level andg = 2.80. In reasonable agrcemcnt with expcrimenr