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5-Amino-5-deoxy-2-C-hydroxymethyl-2,3-O-isopropylidene-l-lyxono-1,5-lactam

✍ Scribed by Simone, Michela ;Fleet, George W. J. ;Bream, Richard ;Watkin, David J.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
298 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The relative configuration of the title compound, C~9~H~14~NO~5~, formed by catalytic hydrogenation of an azidolactone, has been established by X-ray crystallographic analysis. The absolute configuration was determined by the use of 2,3-O-isopropylidene-L-lyxono-1,4-lactone as the carbohydrate starting material.

📜 SIMILAR VOLUMES

5-Amino-5-deoxy-2-C-hydroxy­methyl-2,3-O
5-Amino-5-deoxy-2-C-hydroxy­methyl-2,3-O-iso­propyl­idene-d-talono-1,5-lactam
✍ Ameijde, Jeroen van ;Cowley, Andrew R. ;Fleet, George W. J. ;Nash, Robert J. ;Si 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 181 KB

The title compound, C 10 H 17 NO 6 , was prepared by carrying out three S N 2 displacements on a branched sugar derivative, one of which was not planned. Its crystal structure was determined to con®rm the identity and stereochemistry of the product.

Hydroxy Group Interactions in Stannylate
Hydroxy Group Interactions in Stannylated Carbohydrates. Structures and Thermal Stabilities of 5-Deoxy-5-C- (Ph3Sn)-1,2-O-isopropylidene-α-D-xylofuranose, 5-Deoxy-5-C-(IPh2Sn)-1,2,O-isopropylidene-α-D- and -L-xylofuranose, and 5-Deoxy-5-C-(I2PhSn)-1,2-O-isopropylidene-α-D- and -L-xylofuranose.
✍ Lynne A. Burnett; Vitor F. Ferreira; R. Alan Howie; Helena Rufino; Janet M. S. S 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 62 KB 👁 2 views

## Carbohydrates U 0500 Hydroxy Group Interactions in Stannylated Carbohydrates